Publicación: COMPREHENSIVE TWO-DIMENSIOL GAS CHROMATOGRAPHY AND THREE-DIMENSIONAL FLUOROMETRY FOR DETECTION OF VOLATILE AND BIOACTIVE SUSTANCES IN SOME BERRIES
| dc.creator | PATRICIA EUGENIA PAULINA ARANCIBIA ÁVILA | |
| dc.creator | JOSÉ FERNANDO TOLEDO MONTIEL | |
| dc.date | 2015 | |
| dc.date.accessioned | 2025-01-10T14:34:47Z | |
| dc.date.available | 2025-01-10T14:34:47Z | |
| dc.date.issued | 2015 | |
| dc.description.abstract | THE VOLATILE FRACTIONS OF CAPE GOOSEBERRY AND BLUEBERRY WERE DETERMINED BY HEADSPACE SOLID-PHASE MICROEXTRACTION COUPLED WITH COMPREHENSIVE TWO-DIMENSIONAL GAS CHROMATOGRAPHY WITH TIME-OF-FLIGHT MASS SPECTROMETRY (HS-SPME/GC×GC-TOFMS). THE HIGHEST AMOUNT OF ALCOHOL (51.8%), ESTER (32.8%) AND CARBOXYLIC ACID (6.9%) WAS IN BLUEBERRY IN COMPARISON WITH GOOSEBERRY AND OPPOSITELY KETONES (14.7%), ALDEHYDES (9.9%) AND TERPENES (8%) WERE FOUND IN GOOSEBERRY. THE BIOACTIVE COMPOUNDS AND ANTIOXIDANT CAPACITIES WERE HIGHER IN BLUEBERRIES THAN IN GOOSEBERRIES. THREE DIMENSIONAL FLUORESCENCE EMISSION SPECTROMETRY (3D-FL) WAS APPLIED TO DETERMINE AND TO COMPARE EXPERIMENTALLY FOUND BINDING PARAMETERS OF BERRIES EXTRACTS WITH HUMAN SERUM ALBUMIN (HSA). THE FLUORESCENCE QUENCHING OF HSA BY POLYPHENOLS FROM BERRIES WAS A RESULT OF THE FORMATION OF A POLYPHENOL?HSA COMPLEX. THE BINDING ABILITIES OF BERRIES WERE HIGHLY CORRELATED WITH THE BIOACTIVITY OF POLYPHENOLS AND VOLATILE SUBSTANCES. THE CLUSTER ANALYSIS (CA) AND LINEAR DISCRIMINANT ANALYSIS (LDA) WAS APPLIED TO DIFFERENTIATE THE BERRIES SAMPLES ACCORDING TO THEIR TYPE. | |
| dc.format | application/pdf | |
| dc.identifier.doi | 10.1016/j.talanta.2014.11.061 | |
| dc.identifier.issn | 1873-3573 | |
| dc.identifier.issn | 0039-9140 | |
| dc.identifier.uri | https://repositorio.ubiobio.cl/handle/123456789/8043 | |
| dc.language | spa | |
| dc.publisher | TALANTA | |
| dc.relation.uri | 10.1016/j.talanta.2014.11.061 | |
| dc.rights | PUBLICADA | |
| dc.subject | VOLATILE SUBSTANCES | |
| dc.subject | TWO-DIMENSIONAL GAS CHROMATOGRAPHY | |
| dc.subject | THREE-DIMENSIONAL FLUORESCENCE SPECTROSCOPY | |
| dc.subject | BIOACTIVITY | |
| dc.title | COMPREHENSIVE TWO-DIMENSIOL GAS CHROMATOGRAPHY AND THREE-DIMENSIONAL FLUOROMETRY FOR DETECTION OF VOLATILE AND BIOACTIVE SUSTANCES IN SOME BERRIES | |
| dc.type | ARTÍCULO | |
| dspace.entity.type | Publication | |
| ubb.Estado | PUBLICADA | |
| ubb.Otra Reparticion | DEPARTAMENTO DE CIENCIAS BASICAS | |
| ubb.Otra Reparticion | DEPARTAMENTO DE CIENCIAS BASICAS | |
| ubb.Sede | CHILLÁN | |
| ubb.Sede | CHILLÁN |
