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DESIGN OF FE36.29CR28.9NI26.15CU4.17TI1.67V2.48C0.46 HEA USING A NEW CRITERION BASED ON VEC: MICROSTRUCTURAL STUDY AND MULTISCALE MECHANICAL RESPONSE

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dc.creatorANGELO GIOVANNI OÑATE SOTO
dc.date2023
dc.date.accessioned2025-01-10T15:45:30Z
dc.date.available2025-01-10T15:45:30Z
dc.date.issued2023
dc.description.abstractTHE PRESENT WORK UPDATED EMPIRICAL PARAMETER RANGES WITH A HIGH ADJUSTMENT TO THE EXPERIMENTAL RESULTS AS OBTAINED BY THE MEANS OF THE EXPLORATORY DATA ANALYSIS (EDA) METHOD. A NEW HIGH ENTROPY ALLOY WITH FCC STRUCTURE REINFORCED BY PRECIPITATION OF INTERMETALLIC PHASES FABRICATED BY VACUUM-ARGON INDUCTION MELTING WAS DESIGNED AND MODELED. THE MAIN RESULTS SHOWED THAT THE VALENCE ELECTRON CONCENTRATION (VEC) IS THE PREDOM-INANT EMPIRICAL PHASE PREDICTION PARAMETER IN HIGH ENTROPY ALLOYS AND THAT THE LATTICE PACKING FACTOR IS NECESSARY TO DETERMINE THE PRESENCE OF INTERMETALLIC PHASES EFFECTIVELY. PHASE STABILITY RANGES BASED ON VEC ASSOCIATED WITH THE BASE CRYSTAL STRUCTURES AND THE PRESENCE OF INTERMETALLICS CORROBORATED COMPUTATIONALLY BY CALPHAD AND EXPERIMENTALLY WERE REPORTED. THE INTERDENDRITIC ZONE PROVED TO BE A PREFERENTIAL PRECIPITATION ZONE WITH PRE-CIPITATES OF SIGMA, TIC, AND GAMMA' PHASES. THE GAMMA' PHASE SHOWED A SIZE DIFFERENCE BETWEEN THE DENDRITIC AND INTERDENDRITIC ZONE ASSOCIATED WITH DIFFUSIVE TI MECHANISMS. THE NANOSCALE MECHANICAL RESPONSE DETERMINED THAT DISLOCATION CREEP AND REINFORCEMENT IN THE INTERDENDRITIC ZONE ARE PREDOMINANT CREEP MECHANISMS THAT OBTAINED AN EFFECTIVE ENTANGLEMENT OF THE DISLOCATIONS INCREASING THE STRAIN HARDENING COEFFICIENT. THE MECHANICAL RESPONSE OF THE ALLOY OBTAINED IS SUPERIOR TO THE AVERAGE OF THE ALLOYS WITH FCC STRUCTURE. IT MAINTAINS A HIGH DUCTILITY THAT ALLOWS REACHING AN ENERGY ABSORPTION AND DAMAGE TOLERANCE OF 43.56 GPA% SHOWING SEVERE PLASTIC SLIP LINES BEING IN THE RANGE OF USE FOR AEROSPACE APPLICATIONS AND HYDROGEN TANKS.
dc.formatapplication/pdf
dc.identifier.doi10.1016/j.mtcomm.2023.105681
dc.identifier.issn2352-4928
dc.identifier.urihttps://repositorio.ubiobio.cl/handle/123456789/13521
dc.languagespa
dc.publisherMATERIALS TODAY COMMUNICATIONS
dc.relation.uri10.1016/j.mtcomm.2023.105681
dc.rightsPUBLICADA
dc.subjectPhase prediction
dc.subjectNanoindentation
dc.subjectMechanical reinforcement
dc.subjectHigh entropy alloys
dc.titleDESIGN OF FE36.29CR28.9NI26.15CU4.17TI1.67V2.48C0.46 HEA USING A NEW CRITERION BASED ON VEC: MICROSTRUCTURAL STUDY AND MULTISCALE MECHANICAL RESPONSE
dc.typeARTÍCULO
dspace.entity.typePublication
ubb.EstadoPUBLICADA
ubb.Otra ReparticionDEPARTAMENTO DE INGENIERIA MECANICA
ubb.SedeCONCEPCIÓN
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