Publicación:
ONE-POT AMINATION OF CYCLOHEXANONE-TO-SECONDARY AMINES OVER CARBON-SUPPORTED PD: UNRAVELING THE REACTION MECHANISM AND KINETICS

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dc.creatorMARAY ORTEGA DÍAZ
dc.creatorRAYDEL MANRIQUE SUAREZ
dc.creatorFRANCISCA MARÍA CASTILLO PUCHI
dc.creatorCAMILA BELÉN BERTIOLA NÚÑEZ
dc.creatorLUIS ERNESTO ARTEAGA PÉREZ
dc.date2021
dc.date.accessioned2025-01-10T15:24:54Z
dc.date.available2025-01-10T15:24:54Z
dc.date.issued2021
dc.description.abstractTHE LIQUID PHASE AMINATION OF THE CYCLOHEXANONE (CYO) WITH ANILINE (PHNH2) WAS STUDIED ON A PD/C CATALYST USING NACO2H AS A H-DONOR. CATALYTIC TESTS WERE PERFORMED IN BATCH REACTORS BY VARYING REACTANT CONCENTRATIONS (0, 0.1, 0.2 AND 0.4 MOL/L), THE TEMPERATURE (80?160 °C) AND H2-EQUIVALENTS AVAILABILITY (0, 2 AND 4 H2-EQUIVALENTS WITH RESPECT TO CYO). THE RESULTS INDICATE THAT, THE USE OF NACO2H BARELY AFFECT THE REACTIVITY (MEASURED AS INITIAL REACTION RATE) WHILE IT DOES INFLUENCE THE SELECTIVITY TO SECONDARY AMINES. THIS EFFECT WAS ASCRIBED TO THE LIMITED EFFECTIVITY OF THE H2 TRANSFER, WHICH WAS CONTROLLED BY THE WATER FORMED AFTER THE CONDENSATION OF THE CYO WITH THE PHNH2, HYDROGEN SOLUBILITY IN TOLUENE, AND THE MASS TRANSFER FROM THE LIQUID TO THE CATALYST SURFACE. THE EXPERIMENTAL OBSERVATIONS WERE CONSISTENT WITH A MULTI-STEP MECHANISM CONSISTING IN: A FIRST STEP OF CONDENSATION OF THE KETONE AND THE AMINE TO FORM AN IMINE, FOLLOWED BY THE DISPROPORTIONATION OF THE IMINE INTO SECONDARY AMINES. THE KINETIC MEASUREMENTS AT INITIAL RATE CONDITIONS WERE WELL INTERPRETED BY A LANGMUIR HINSHELWOOD (L-H) KINETIC MODEL, WHICH SUGGEST THAT THE SURFACE REACTION TO FORM THE INTERMEDIARY IMINE IS THE RATE LIMITING STEP (R.L.S).
dc.formatapplication/pdf
dc.identifier.doi10.1016/j.cej.2021.129236
dc.identifier.issn1873-3212
dc.identifier.issn1385-8947
dc.identifier.urihttps://repositorio.ubiobio.cl/handle/123456789/11905
dc.languagespa
dc.publisherCHEMICAL ENGINEERING JOURNAL
dc.relation.uri10.1016/j.cej.2021.129236
dc.rightsPUBLICADA
dc.titleONE-POT AMINATION OF CYCLOHEXANONE-TO-SECONDARY AMINES OVER CARBON-SUPPORTED PD: UNRAVELING THE REACTION MECHANISM AND KINETICS
dc.title.alternativeAMINACIÓN DE UNA SOLA OLLA DE CICLOHEXANONA A AMINAS SECUNDARIAS SOBRE PD SOPORTADA POR CARBONO: DESENTRAÑANDO EL MECANISMO DE REACCIÓN Y LA CINÉTICA
dc.typeARTÍCULO
dspace.entity.typePublication
ubb.EstadoPUBLICADA
ubb.Otra ReparticionDEPARTAMENTO DE INGENIERIA EN MADERAS
ubb.Otra ReparticionRECTORIA
ubb.Otra ReparticionDEPARTAMENTO DE INGENIERIA EN MADERAS
ubb.Otra ReparticionDEPARTAMENTO DE INGENIERIA EN MADERAS
ubb.Otra ReparticionDEPARTAMENTO DE INGENIERIA EN MADERAS
ubb.SedeCONCEPCIÓN
ubb.SedeCONCEPCIÓN
ubb.SedeCONCEPCIÓN
ubb.SedeCONCEPCIÓN
ubb.SedeCONCEPCIÓN
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