Publicación:
EXPERIMENTAL PROTOCOL FOR THE STUDY OF ONE-POT AMINATION OF CYCLOHEXANONE-TO-SECONDARY AMINES OVER CARBON-SUPPORTED PD

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dc.creatorMARAY ORTEGA DÍAZ
dc.creatorRAYDEL MANRIQUE SUAREZ
dc.creatorFRANCISCA MARÍA CASTILLO PUCHI
dc.creatorCAMILA BELÉN BERTIOLA NÚÑEZ
dc.creatorLUIS ERNESTO ARTEAGA PÉREZ
dc.date2021
dc.date.accessioned2025-01-10T15:21:55Z
dc.date.available2025-01-10T15:21:55Z
dc.date.issued2021
dc.description.abstractTHE VALIDATION OF PROTOCOLS FOR CARRYING OUT THE EXPERIMENTAL ANALYSIS OF AMINATION REACTIONS IS OF PARAMOUNT IMPORTANCE TO ENHANCE THE SCIENTIFIC KNOWLEDGE AND REPRODUCIBILITY OF RESULTS. ACCORDINGLY, IN THE PRESENT PAPER, A PROTOCOL HAS BEEN PROPOSED FOR THE STUDY OF THE AMINATION OF CYCLOHEXANONE-TO-SECONDARY AMINES (DIPHENYLAMINE AND N-CYCLOHEXYLANILINE) OVER HETEROGENEOUS CATALYSTS. THE RESULTS OF ACTIVITY AND SELECTIVITY, AND THE ELUCIDATION OF A PLAUSIBLE REACTION PATHWAY WERE DESCRIBED IN A PARENT PAPER. THEREFORE, THE PURPOSE OF THIS DOCUMENT IS TO INFORM ABOUT THE DETAILS OF THE EXPERIMENTAL SETUPS, THE METHODS, AND THE ANALYTICAL TECHNIQUES TO IDENTIFY AND QUANTIFY THE REACTION PRODUCTS. FINALLY, SOME PRACTICAL AND SAFETY CONSIDERATIONS ARE ALSO INCLUDED. ? ONE-POT CATALYTIC AMINATION OF CYCLOHEXANONE WITH ANILINE WAS PERFORMED EFFICIENTLY IN LIQUID PHASE ON PD/C. ? STIRRING, HE ATMOSPHERE AND TEMPERATURE CONTROL WERE CRITICAL TO ACHIEVE REPRODUCIBLE ACTIVITY RESULTS. ? ULTRA-HIGH PERFORMANCE LIQUID CHROMATOGRAPHY ALLOWS IDENTIFYING PRODUCTS AND REACTION INTERMEDIATES, WHILE NONANE PERFORMED WELL AS INTERNAL STANDARD FOR GC-FID QUANTIFICATION.
dc.formatapplication/pdf
dc.identifier.doi10.1016/j.mex.2021.101406
dc.identifier.issn2215-0161
dc.identifier.urihttps://repositorio.ubiobio.cl/handle/123456789/11667
dc.languagespa
dc.publisherMETHODXS
dc.relation.uri10.1016/j.mex.2021.101406
dc.rightsPUBLICADA
dc.titleEXPERIMENTAL PROTOCOL FOR THE STUDY OF ONE-POT AMINATION OF CYCLOHEXANONE-TO-SECONDARY AMINES OVER CARBON-SUPPORTED PD
dc.typeARTÍCULO
dspace.entity.typePublication
ubb.EstadoPUBLICADA
ubb.Otra ReparticionDEPARTAMENTO DE INGENIERIA EN MADERAS
ubb.Otra ReparticionDEPARTAMENTO DE INGENIERIA EN MADERAS
ubb.Otra ReparticionDEPARTAMENTO DE INGENIERIA EN MADERAS
ubb.Otra ReparticionDEPARTAMENTO DE INGENIERIA EN MADERAS
ubb.Otra ReparticionDEPARTAMENTO DE INGENIERIA EN MADERAS
ubb.SedeCONCEPCIÓN
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