Publicación:
A PHOTOCHEMICAL APPROACH TO THE SYNTHESIS OF ZNO/CUO FILMS AND THEIR APPLICATION TO THE PHOTOCATALYTIC DEGRADATION OF RHODAMINES (RH-B AND RH-6G) UNDER UV-VIS LIGHT IRRADIATION

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dc.creatorCAMILA CONSTANZA CIFUENTES BÓRQUEZ
dc.creatorMARCELA TERESA DE JESÚS MATUS SALAZAR
dc.creatorCRISTIAN ANDRÉS SUÁREZ ZÚÑIGA
dc.creatorCLAUDIA ANDREA CARO DÍAZ
dc.creatorGERARDO ANDRÉS CABELLO GUZMÁN
dc.date2023
dc.date.accessioned2025-01-10T15:36:23Z
dc.date.available2025-01-10T15:36:23Z
dc.date.issued2023
dc.description.abstractWE PROPOSE THE SYNTHESIS OF B-TRIKETONATE COMPLEXES OF ZN(II) AND CU(II) AS PRECURSORS IN THE PHOTO-DEPOSITION OF ZNO FILMS LOADED WITH CUO, WHICH ARE SUBSEQUENTLY CALCINED AT 600 C. THE ZNO/CUO HETEROJUNCTION SYSTEM WAS ANALYZED BY XRD, SEM AND XPS; THE RESULTS DEMONSTRATE LOW CRYSTALLINITY OF THE FILMS AND THE FORMATION OF ZNO AND CUO. THE RESULTS OF OPTICAL PROPERTIES CONFIRM A GRADUAL REDUCTION OF THE OPTICAL BANDGAP WHEN CUO LOADING IS INCREASED IN THE ZNO MATRIX AND THE PHOTOLUMINESCENCE TESTS FOUND A DECREASE IN THE EMISSION BANDS OF THE ZNO MATRIX WITH THE INSERTION OF CUO. THE MAXIMUM PHOTO-DEGRADATION EFFICIENCY IS ACHIEVED FOR ZNO FILMS LOADED WITH CUO AT 1 MOL%, OBTAINING 75.4 AND 68.3% FOR RHODAMINE B AND RHODAMINE 6G, RESPECTIVELY. WE PROPOSE THAT ZNO IS RESPONSIBLE FOR THE FORMATION OF SUPEROXIDE RADICALS AS THE MAIN REACTIVE SPECIES IN THE DEGRADATION OF BOTH RHODAMINES.
dc.formatapplication/pdf
dc.identifier.doi10.1016/j.inoche.2023.110695
dc.identifier.issn1879-0259
dc.identifier.issn1387-7003
dc.identifier.urihttps://repositorio.ubiobio.cl/handle/123456789/12806
dc.languagespa
dc.publisherINORGANIC CHEMISTRY COMMUNICATIONS
dc.relation.uri10.1016/j.inoche.2023.110695
dc.rightsRESTRICTED ACCESS
dc.subjectRhodamine B
dc.subjectRhodamine 6G
dc.subjectPhoto-deposition
dc.subjectHeterojunction
dc.subjectFilms
dc.titleA PHOTOCHEMICAL APPROACH TO THE SYNTHESIS OF ZNO/CUO FILMS AND THEIR APPLICATION TO THE PHOTOCATALYTIC DEGRADATION OF RHODAMINES (RH-B AND RH-6G) UNDER UV-VIS LIGHT IRRADIATION
dc.typeCOMUNICACIÓN CORTA
dspace.entity.typePublication
oaire.fundingReferenceANID- AGENCIA NACIONAL DE INVESTIGACIÓN Y DESARROLLO (EX CONICYT)
ubb.EstadoPUBLICADA
ubb.Otra ReparticionDEPARTAMENTO DE CIENCIAS BASICAS
ubb.Otra ReparticionDEPARTAMENTO DE CIENCIAS BASICAS
ubb.Otra ReparticionDEPARTAMENTO DE CIENCIAS BASICAS
ubb.Otra ReparticionDEPARTAMENTO DE CIENCIAS BASICAS
ubb.Otra ReparticionDEPARTAMENTO DE CIENCIAS BASICAS
ubb.SedeCHILLÁN
ubb.SedeCHILLÁN
ubb.SedeCHILLÁN
ubb.SedeCHILLÁN
ubb.SedeCHILLÁN
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