Publicación: DATASET ON THE REDUCTIVE AMINATION OF PHENOLICS WITH CYCLOHEXYLAMINE OVER RH/C AND PD/C: CATALYSTS CHARACTERIZATION AND REACTION PERFORMANCE
Fecha
2022
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SECONDARY AMINES PLAY A VERY IMPORTANT ROLE IN TODAY?S CHEMICAL INDUSTRY OWING TO THEIR EXTENSIVE APPLICATIONS IN AGRICULTURAL, PHARMACEUTICAL, TEXTILE, POLYMER AND IN PERSONAL CARE FIELDS [1] UNFORTUNATELY, MOST OF THE AMINE SYNTHESIS PROCESSES AT THE INDUSTRIAL LEVEL ARE FOSSIL-BASED AND IMPLY ECONOMIC AND ENVIRONMENTAL PROBLEMS. HOWEVER, THE HETEROGENEOUSLY CATALYZED REDUCTIVE AMINATION OF LIGNIN-DERIVED PHENOLICS HAS BEEN RECOGNIZED AS AN EFFICIENT AND ECOFRIENDLY METHOD FOR THE SYNTHESIS OF PRIMARY OR HIGHER ORDER AMINES [2]. IN THIS SENSE, METAL-SUPPORTED CATALYSTS, SPECIFICALLY PALLADIUM, AND RHODIUM-BASED MATERIALS, HAVE DEMONSTRATED THEIR EFFECTIVITY TO PRODUCE SECONDARY AMINES [3,4]. THEREFORE, THERE IS A CRESCENT INTEREST IN EVALUATING THEIR ROLES WITHIN THE REACTION MECHANISMS BY TESTING DIFFERENT REACTION CONDITIONS AND PHENOLICS SOURCES NEVERTHELESS, THERE IS A LACK OF EXPERIMENTAL DATA ALLOWING TO ESTABLISH A CORRELATION BETWEEN THE NATURE OF THE METALLIC CLUSTERS, THE OPERATIONAL PARAMETERS, AND STERIC EFFECTS OF ALKYL-PHENOLICS WITH THE ACTIVITY AND SELECTIVITY TO AMINES. ACCORDINGLY, THIS DATASET INCLUDES RELIABLE EXPERIMENTAL MEASUREMENTS ON THE USE OF PD/C AND RH/C AS CATALYSTS FOR ........
