Publicación: DATASET ON THE REDUCTIVE AMINATION OF PHENOLICS WITH CYCLOHEXYLAMINE OVER RH/C AND PD/C: CATALYSTS CHARACTERIZATION AND REACTION PERFORMANCE
| dc.creator | MARAY ORTEGA DÍAZ | |
| dc.creator | LUIS ERNESTO ARTEAGA PÉREZ | |
| dc.date | 2022 | |
| dc.date.accessioned | 2025-01-10T15:35:57Z | |
| dc.date.available | 2025-01-10T15:35:57Z | |
| dc.date.issued | 2022 | |
| dc.description.abstract | SECONDARY AMINES PLAY A VERY IMPORTANT ROLE IN TODAY?S CHEMICAL INDUSTRY OWING TO THEIR EXTENSIVE APPLICATIONS IN AGRICULTURAL, PHARMACEUTICAL, TEXTILE, POLYMER AND IN PERSONAL CARE FIELDS [1] UNFORTUNATELY, MOST OF THE AMINE SYNTHESIS PROCESSES AT THE INDUSTRIAL LEVEL ARE FOSSIL-BASED AND IMPLY ECONOMIC AND ENVIRONMENTAL PROBLEMS. HOWEVER, THE HETEROGENEOUSLY CATALYZED REDUCTIVE AMINATION OF LIGNIN-DERIVED PHENOLICS HAS BEEN RECOGNIZED AS AN EFFICIENT AND ECOFRIENDLY METHOD FOR THE SYNTHESIS OF PRIMARY OR HIGHER ORDER AMINES [2]. IN THIS SENSE, METAL-SUPPORTED CATALYSTS, SPECIFICALLY PALLADIUM, AND RHODIUM-BASED MATERIALS, HAVE DEMONSTRATED THEIR EFFECTIVITY TO PRODUCE SECONDARY AMINES [3,4]. THEREFORE, THERE IS A CRESCENT INTEREST IN EVALUATING THEIR ROLES WITHIN THE REACTION MECHANISMS BY TESTING DIFFERENT REACTION CONDITIONS AND PHENOLICS SOURCES NEVERTHELESS, THERE IS A LACK OF EXPERIMENTAL DATA ALLOWING TO ESTABLISH A CORRELATION BETWEEN THE NATURE OF THE METALLIC CLUSTERS, THE OPERATIONAL PARAMETERS, AND STERIC EFFECTS OF ALKYL-PHENOLICS WITH THE ACTIVITY AND SELECTIVITY TO AMINES. ACCORDINGLY, THIS DATASET INCLUDES RELIABLE EXPERIMENTAL MEASUREMENTS ON THE USE OF PD/C AND RH/C AS CATALYSTS FOR ........ | |
| dc.format | application/pdf | |
| dc.identifier.doi | 10.1016/j.dib.2022.108620 | |
| dc.identifier.issn | 2352-3409 | |
| dc.identifier.uri | https://repositorio.ubiobio.cl/handle/123456789/12773 | |
| dc.language | spa | |
| dc.publisher | DATA IN BRIEF | |
| dc.relation.uri | 10.1016/j.dib.2022.108620 | |
| dc.rights | PUBLICADA | |
| dc.title | DATASET ON THE REDUCTIVE AMINATION OF PHENOLICS WITH CYCLOHEXYLAMINE OVER RH/C AND PD/C: CATALYSTS CHARACTERIZATION AND REACTION PERFORMANCE | |
| dc.type | ARTÍCULO | |
| dspace.entity.type | Publication | |
| ubb.Estado | PUBLICADA | |
| ubb.Otra Reparticion | DEPARTAMENTO DE INGENIERIA EN MADERAS | |
| ubb.Otra Reparticion | DEPARTAMENTO DE INGENIERIA EN MADERAS | |
| ubb.Sede | CONCEPCIÓN | |
| ubb.Sede | CONCEPCIÓN |
